Hi Maxim, Sorry for the delay in answering, my computer decided it didn't want to listen to me anymore. I finally convinced it otherwise.
To answer your first question, I have run across some foul smelling resins. Fortunately, none required oven treatment. Anything I've put in the oven hasn't caused much odor. If it did, I'd probably run a clean cycle to burn it out. Any oven cleaner I've smelled is much worse than most resins.
As far as memory goes, I'm not a chemist, but this is what I've learned. (Full Disclosure, Some of the fancier words/sentences have been plagiarized)
There may be many resins that exhibit Memory traits. However, I don’t believe many in our hobby do.
Crosslink density varies depending on the monomer or prepolymer mix, and the mechanism of crosslinking. The higher the crosslink density and aromatic (organic compound) content of a thermoset polymer, the higher the resistance to heat degradation and chemical attack. Mechanical strength and hardness also improve with crosslink density, although at the expense of brittleness. They normally decompose before melting.
The degree of crosslinking and resulting physical type (elastomer or plastic) is adjusted from the molecular weight and functionality of isocyanate resins, prepolymers, and the exact combinations of diols, triols and polyols selected, with the rate of reaction being strongly influenced by catalysts and inhibitors.
Thermosetting polymer mixtures based on thermosetting resin monomers and pre-polymers can be formulated and applied and processed in a variety of ways to create distinctive cured properties.
Conventional thermoset plastics or elastomers cannot be melted and re-shaped after they are cured. However, Some thermoset polyurethanes have transient properties, which allow moderate reforming. Some hard, plastic thermosets may undergo permanent or plastic deformation under load. Most Formulas used in our hobby undergo permanent deformation when heated and under load.
One thing to keep in mind, there are so many formulas out there that someone might use a different kind of resin than we are used to. One that may not deform under heat or might retain a strong memory.
So to sum it up, The better resins used are formulated in such a way to allow a bit of reforming. Heating and cooling need to be done slowly for best results. And finally, there are many variables that can interfere and cause issues, but some people are just luckier than others.
